Home Categories Inorganic chemistry Trichlorosilane
T9943830

Trichlorosilane , >98.0%(T) , 10025-78-2

CAS NO.:10025-78-2

Empirical Formula: Cl3HSi

Molecular Weight: 135.45

MDL number: MFCD00011518

EINECS: 233-042-5

Update time: 2022-07-08

PRODUCT Properties

Melting point: −126.6 °C (−195.9 °F; 146.6 K)
Boiling point: 31.8 °C (89.2 °F; 304.9 K)
Density  1.342 g/cm3
vapor density  1 (vs air)
vapor pressure  9.75 psi ( 20 °C)
refractive index  1.40
Flash point: −27 °C (−17 °F; 246 K)
storage temp.  Refrigerator
solubility  Soluble in benzene, ether, heptane, chloroform and carbon tetrachloride.
form  liquid
Specific Gravity 1.342
color  colourless
Odor Sharp, choking, like hydrochloric acid.
explosive limit 70%
Water Solubility  decomposes
Specific Heat Capacity Cp(gas): 0.56 J/(g·K), at 25℃
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
Sensitive  Air & Moisture Sensitive
Merck  14,9646
Stability: Stable, but extremely flammable. Pyrophoric - spontaneously ignites in air. Explosion hazard in air - note wide explosion limits. Reacts violently with water. Incompatible with moisture, acids, bases, strong oxidizing agents, alcohols, amines.
InChIKey ZDHXKXAHOVTTAH-UHFFFAOYSA-N
CAS DataBase Reference 10025-78-2(CAS DataBase Reference)
NIST Chemistry Reference Trichlorosilane(10025-78-2)
EPA Substance Registry System Trichlorosilane (10025-78-2)

Description and Uses

Trichlorosilane is used in process of hydrosilylation. It is also used for reductive hydrazination which is a high yielding method for preparation of 1,1-disubstituted hydrazines.

Safety

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)Skull and Crossbones (GHS06)Health Hazard (GHS08)
GHS02,GHS05,GHS06,GHS08
Signal word  Danger
Hazard statements  H331-H302-H314-H370-H372-H335-H224-H250-H260
Precautionary statements  P501-P223-P222-P260-P270-P240-P231+P232-P210-P233-P243-P241-P242-P271-P264-P280-P370+P378-P335+P334-P308+P311-P303+P361+P353-P302+P334-P301+P330+P331-P363-P301+P312+P330-P304+P340+P310-P305+P351+P338+P310-P403+P233-P422-P402+P404-P403+P235-P405
Hazard Codes  F+,C
Risk Statements  12-14-17-20/22-29-35
Safety Statements  16-26-36/37/39-43-45-7/9-43A
RIDADR  UN 1295
WGK Germany  1
RTECS  VV5950000
F  4.5-21-31
TSCA  TSCA listed
HazardClass  4.3
PackingGroup  I
HS Code  28530090
Hazardous Substances Data 10025-78-2(Hazardous Substances Data)
Toxicity LD50 orally in rats: 1.03 g/kg (Smyth)
REACH Registrations Active
Excepted Quantities Forbidden

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