1,1′-bis(di-cyclohexylphosphino)ferrocenepalladiumdichloride , 99% , 917511-90-1

Synonym(s):
PdCl₂(dcypf)

CAS NO.：917511-90-1

Empirical Formula: 2C17H26P.Cl2Pd.Fe

Molecular Weight: 755.904

MDL number: MFCD11656081

PRODUCT Properties

• Melting point: 294-300 °C
• storage temp.: -20°C
• form: Crystalline solid
• color: red-orange microcrystal
• InChI: InChI=1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2
• InChIKey: HRAMBTUEZQOQRK-UHFFFAOYSA-L
• SMILES: [CH]1[CH][CH][CH][C]1P(C1CCCCC1)C1CCCCC1.[CH]1[CH][CH][CH][C]1P(C1CCCCC1)C1CCCCC1.[Pd](Cl)Cl.[Fe] |^1:0,1,2,3,4,18,19,20,21,22|
• CAS DataBase Reference: 917511-90-1

Description and Uses

1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl₂) can be used as a catalyst in the synthesis of:

• α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
• Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH₂ group and arylboronic acids.
• α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P305+P351+P338
• WGK Germany: 3