[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) , 97% , 67292-34-6

Synonym(s):
Ni(dppf)Cl₂

CAS NO.：67292-34-6

Empirical Formula: C34H22Cl2FeNiP2

Molecular Weight: 677.94

MDL number: MFCD00270284

PRODUCT Properties

• Melting point: 285 °C (dec.)(lit.)
• storage temp.: Inert atmosphere,Room Temperature
• form: crystal
• color: green micro
• Water Solubility: Insoluble in water.
• Exposure limits: NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
• InChI: InChI=1S/2C17H11P.2ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-6,9-12,18H;2*1H;;/q;;;;+2;/p-2
• InChIKey: YLRDSVJNPNAGLK-UHFFFAOYSA-L
• SMILES: [Cl-][Ni+2]1(P(C2C=CC=CC=2)(C2C=CC=CC=2)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]8(C9=3)P1(C1C=CC=CC=1)C1C=CC=CC=1)[Cl-]

Description and Uses

(1,1''-Bis(diphenylphosphino)ferrocene)dichloronickel(II) is an organometallic catalyst used in a variety of synthetic applications, such as the gem-?difluoropropargylation of alkylzinc reagents, or cross coupling reactions to form 2,?3,?5,?6-?tetrasubstituted dehydropiperidines.

Safety

• Symbol(GHS): GHS08
• Signal word: Danger
• Hazard statements: H317-H334-H350
• Precautionary statements: P201-P280-P302+P352-P308+P313
• Hazard Codes: T
• Risk Statements: 45-42/43
• Safety Statements: 53-22-36/37/39-45
• RIDADR: 2811
• WGK Germany: 3
• HS Code: 29319090