RuCl[(R,R)-Tsdpen(mesitylene) , ≥90.0% , 174813-82-2

CAS NO.：174813-82-2

Empirical Formula: C30H30ClN2O3RuS-

Molecular Weight: 635.159

MDL number: MFCD12545951

PRODUCT Properties

• Melting point: 241-249°C
• storage temp.: 2-8°C
• form: Powder
• color: orange
• Sensitive: air sensitive
• InChIKey: HTPIQYBAGIDYTK-IDJGTMRTNA-L
• SMILES: CC1=CC(C)=CC(C)=C1.[Ru-]1(Cl)NC(=O)C2=CC=C(S1(=O)=O)C([C@@H](C1=CC=CC=C1)[C@@H](N)C1=CC=CC=C1)=C2 |&1:22,29,r|

Description and Uses

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:

• (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
• Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H302-H315-H319-H335
• Precautionary statements: P261-P305+P351+P338
• WGK Germany: 3
• HS Code: 2931.90.6000