Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) , 98% , 1375325-71-5

Synonym(s):
Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)

CAS NO.：1375325-71-5

Empirical Formula: C24H37ClNPPd

Molecular Weight: 512.41

MDL number: MFCD21608496

PRODUCT Properties

• Melting point: 158-160°C
• storage temp.: 2-8°C, protect from light, stored under nitrogen
• form: Powder
• color: yellow
• InChI: InChI=1S/C12H9N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9,13H;1-9H3;1H;/q-2;;;+2
• InChIKey: CCFGXRYKSYUWKT-UHFFFAOYSA-N
• SMILES: P([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-])(C(C)(C)C)(C(C)(C)C)C(C)(C)C

Description and Uses

P(t-Bu)₃ Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)₃) may be used as catalyst in the following studies:

• Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides.
• Stille cross-couplings reactions of aryl chloride.
• Synthesis of chloropeptin I, via Stille cross-coupling reaction.
• Heck reaction.
• Negishi cross-coupling reactions.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319
• Precautionary statements: P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
• WGK Germany: 3
• HS Code: 2931.90.6000