Allyltrimethylsilane , 98% , 762-72-1

Synonym(s):
3-(Trimethylsilyl)propene

CAS NO.：762-72-1

Empirical Formula: C6H14Si

Molecular Weight: 114.26

MDL number: MFCD00008635

EINECS: 212-104-5

PRODUCT Properties

• Boiling point: 84-88 °C (lit.)
• Density: 0.719 g/mL at 25 °C (lit.)
• vapor pressure: 82hPa at 25℃
• refractive index: n20/D 1.407(lit.)
• Flash point: 45 °F
• storage temp.: 2-8°C
• solubility: freely sol all organic solvents.
• form: Liquid
• color: Clear colorless
• Specific Gravity: 0.72
• Water Solubility: insoluble
• Hydrolytic Sensitivity: 2: reacts with aqueous acid
• BRN: 906755
• Stability: Volatile
• InChIKey: HYWCXWRMUZYRPH-UHFFFAOYSA-N
• LogP: 4.64 at 20℃
• CAS DataBase Reference: 762-72-1(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl-2-propenyl-(762-72-1)
• EPA Substance Registry System: Silane, trimethyl-2-propenyl- (762-72-1)

Description and Uses

Allyltrimethylsilane is a general reagent to introduce allyl groups across acid chlorides, aldehydes, ketones, iminium ions, enones, and for cross-coupling with other carbon electrophiles. It is used as a reagent in Hosomi?Sakurai reaction.

Safety

• Symbol(GHS): GHS02,GHS07
• Signal word: Danger
• Hazard statements: H225-H315
• Precautionary statements: P210-P302+P352
• Hazard Codes: F,Xi
• Risk Statements: 11-36/37/38
• Safety Statements: 16-26-36-23-33-7/9
• RIDADR: UN 1993 3/PG 2
• WGK Germany: 3
• TSCA: Yes
• HazardClass: 3
• PackingGroup: II
• HS Code: 29310095
• Limited Quantities: 1.0 L (0.3 gallon) (liquid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)