A0840912
(-)-α-Phellandrene , >65.0%(GC) , 4221-98-1
Synonym(s):
(−)-p-Mentha-1,5-diene;(R)-(-)-alpha-Phellandrene;(R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene
CAS NO.：4221-98-1
Empirical Formula: C10H16
Molecular Weight: 136.23
MDL number: MFCD00062988
EINECS: 224-167-6
| Pack Size | Price | Stock | Quantity |
| 1ML | RMB159.20 | In Stock |
|
| 5ML | RMB559.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| alpha | D20 -217° |
| Boiling point: | 171-174 °C(lit.) |
| Density | 0.844 g/mL at 20 °C(lit.) |
| vapor pressure | 2.35hPa at 20℃ |
| refractive index | n |
| Flash point: | 49 °C |
| storage temp. | 2-8°C |
| solubility | Benzene (Sparingly), Ethyl Acetate (Slightly) |
| form | clear liquid |
| color | Colorless to Light yellow to Light orange |
| Odor | at 100.00 %. terpene spicy medicinal |
| Odor Type | terpenic |
| optical activity | [α]20/D 225±5°, c = 10% in diethyl ether |
| Water Solubility | 4.37mg/L at 20℃ |
| Merck | 14,7200 |
| BRN | 2497824 |
| Cosmetics Ingredients Functions | PERFUMING |
| InChI | 1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4-6,8,10H,7H2,1-3H3/t10-/m1/s1 |
| InChIKey | OGLDWXZKYODSOB-SNVBAGLBSA-N |
| SMILES | CC(C)[C@H]1CC=C(C)C=C1 |
| LogP | 5.74 at 21.6℃ |
| CAS DataBase Reference | 4221-98-1(CAS DataBase Reference) |
| EPA Substance Registry System | 1,3-Cyclohexadiene, 2-methyl-5-(1-methylethyl)-, (5R)- (4221-98-1) |
Description and Uses
(R)-(-)-α-Phellandrene undergoes [4+2] cycloaddition with 2-naphthyl acetylenecarboxylate to form a chiral diene, which can act as a ligand for the rhodium-catalyzed asymmetric addition reactions. It may be used to synthesize (1S,5R)-5-(1-methylethyl)-2-methylidene-3-cyclohexen-1-yl hydroperoxide, which on reduction forms trans-yabunikkeol.
Safety
| Symbol(GHS) |  GHS02 |
| Signal word | Warning |
| Hazard statements | H226 |
| Precautionary statements | P210 |
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
| Risk Statements | 10 |
| RIDADR | UN 2319 3/PG 3 |
| WGK Germany | 3 |
| F | 23 |
| TSCA | TSCA listed |
| HS Code | 2902.19.0050 |
| HazardClass | 3 |
| PackingGroup | III |
| Storage Class | 3 - Flammable liquids |
| Hazard Classifications | Aquatic Acute 1 Aquatic Chronic 1 Asp. Tox. 1 Flam. Liq. 3 Skin Sens. 1B |
