A1180412
4-Bromophbenol , 98% , 106-41-2
Synonym(s):
p-Bromophenol;1-Bromo-4-hydroxybenzene
CAS NO.：106-41-2
Empirical Formula: C6H5BrO
Molecular Weight: 173.01
MDL number: MFCD00002313
EINECS: 203-394-4
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 61-64 °C (lit.) |
| Boiling point: | 235-236 °C (lit.) |
| Density | 1.84 |
| refractive index | 1.5085 (estimate) |
| Flash point: | 235-238°C |
| storage temp. | room temp |
| solubility | 14g/l |
| pka | 9.37(at 25℃) |
| form | Crystalline Solid |
| color | Pinkish-brown |
| Water Solubility | It is insoluble in water. It is soluble in 5%ethanol. |
| λmax | 282nm(EtOH)(lit.) |
| Merck | 14,1428 |
| BRN | 1680024 |
| Henry's Law Constant | 6.7×101 mol/(m3Pa) at 25℃, Abraham et al. (1994) |
| InChI | 1S/C6H5BrO/c7-5-1-3-6(8)4-2-5/h1-4,8H |
| InChIKey | GZFGOTFRPZRKDS-UHFFFAOYSA-N |
| SMILES | Oc1ccc(Br)cc1 |
| CAS DataBase Reference | 106-41-2(CAS DataBase Reference) |
| NIST Chemistry Reference | 4-Bromophenol(106-41-2) |
| EPA Substance Registry System | Phenol, 4-bromo- (106-41-2) |
Description and Uses
4-Bromophenol is used as an intermediate in medicine grade. It is also used as a phenol that is used in Stille reactions. It is used in the intermediate of organic synthesis, flame retardant and pharmaceutical industry.
Safety
| Symbol(GHS) |    GHS07,GHS08,GHS09 |
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H361-H411 |
| Precautionary statements | P501-P273-P270-P202-P201-P264-P280-P302+P352-P391-P308+P313-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330-P405 |
| PPE | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xn,Xi |
| Risk Statements | 22-36/37/38-20/21/22 |
| Safety Statements | 26-37/39-36 |
| RIDADR | 2811 |
| WGK Germany | 2 |
| RTECS | SJ7960000 |
| F | 8-10-23 |
| Hazard Note | Irritant |
| TSCA | TSCA listed |
| HazardClass | 6.1(b) |
| PackingGroup | III |
| HS Code | 29081000 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Acute Tox. 4 Oral Skin Irrit. 2 |
| Hazardous Substances Data | 106-41-2(Hazardous Substances Data) |
| Toxicity | mouse,LD50,intraperitoneal,411mg/kg (411mg/kg),Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 44(12), Pg. 19, 1979. |
