Dichlorobis(triphenylphosphine)nickel(II) , 98% , 14264-16-5

Synonym(s):
Dichlorobis(triphenylphosphine)nickel(II);Nickel(II)bis(triphenylphosphine) dichloride;NiCl₂(PPh₃)₂

CAS NO.：14264-16-5

Empirical Formula: C36H30Cl2NiP2

Molecular Weight: 654.17

MDL number: MFCD00009592

EINECS: 238-154-8

PRODUCT Properties

• Melting point: 250 °C (dec.)(lit.)
• storage temp.: Inert atmosphere,Room Temperature
• solubility: DMSO (Slightly), Methanol (Slightly)
• form: Crystals or Powder
• color: Dark green to dark gray
• Water Solubility: insoluble
• Sensitive: Hygroscopic
• Exposure limits: NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
• InChI: InChI=1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
• InChIKey: ZBRJXVVKPBZPAN-UHFFFAOYSA-L
• SMILES: P(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Ni](Cl)Cl
• CAS DataBase Reference: 14264-16-5(CAS DataBase Reference)
• NIST Chemistry Reference: dichlorobis(triphenylphosphine)nickel(14264-16-5)
• EPA Substance Registry System: Nickel, dichlorobis(triphenylphosphine)- (14264-16-5)

Description and Uses

Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.

Safety

• Symbol(GHS): GHS07,GHS08
• Signal word: Danger
• Hazard statements: H317-H350-H412
• Precautionary statements: P201-P273-P280-P302+P352-P308+P313
• Hazard Codes: T
• Risk Statements: 45-43-52/53-34-20/21/22
• Safety Statements: 53-36/37-45-60-36/37/39-26
• RIDADR: 3260
• WGK Germany: 3
• RTECS: QR6170000
• F: 21
• TSCA: Yes
• HazardClass: 6.1(b)
• PackingGroup: III
• HS Code: 29310095
• Limited Quantities: 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)