Bis(dibenzylideneacetone)palladium(0) , Pd18.5% , 32005-36-0

Synonym(s):
Palladium(0) bis(dibenzylideneacetone);Pd(dba)₂

CAS NO.：32005-36-0

Empirical Formula: C34H20O2Pd

Molecular Weight: 566.95

MDL number: MFCD00051942

EINECS: 608-691-6

PRODUCT Properties

• Melting point: 150°C
• storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• solubility: Chloroform (Slightly)
• form: Fine Powder
• color: Red-brown to black
• Water Solubility: insoluble
• Sensitive: Air & Moisture Sensitive
• Stability: Hygroscopic
• InChI: InChI=1S/2C17H10O.Pd/c2*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;/h2*1-10H
• InChIKey: WTAPZWXVSZMMDG-JZOPPWQGSA-N
• SMILES: O=C1C2=C(C3C=CC=CC=3)[Pd]34562(C(C2C=CC=CC=2)=C3C(=O)C4=C5C2C=CC=CC=2)C(C2C=CC=CC=2)=C16
• CAS DataBase Reference: 32005-36-0(CAS DataBase Reference)

Description and Uses

Hydrogenation, isomerization, carbonylation, oxidation, C-C bond formation.Bis(dibenzylideneacetone)palladium(0) is used as a reagent for the preparation of allylic substituted cyclopentadienes. It acts as a homogeneous catalyst as well as in the alkylation of allyl acetates by various nucleophiles. Further, it is used in Suzuki reaction.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H302+H312+H332-H315-H319
• Precautionary statements: P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501
• PPE: Eyeshields, Gloves, type N95 (US)
• Hazard Codes: Xi
• Risk Statements: 36/38
• Safety Statements: 22-24/25-37/39-26
• WGK Germany: 3
• TSCA: No
• HS Code: 28439000
• Storage Class: 11 - Combustible Solids