4-Bromo-4'-hydroxybiphenyl , >99.0%(GC) , 29558-77-8

CAS NO.：29558-77-8

Empirical Formula: C12H9BrO

Molecular Weight: 249.1

MDL number: MFCD00059076

EINECS: 608-376-3

PRODUCT Properties

• Melting point: 164-166 °C(lit.)
• Boiling point: 355.5±17.0 °C(Predicted)
• Density: 1.4188 (rough estimate)
• refractive index: 1.5130 (estimate)
• storage temp.: Sealed in dry,Room Temperature
• pka: 9.70±0.15(Predicted)
• form: powder to crystal
• color: White to Almost white
• Water Solubility: Soluble in water (partly), and methanol.
• InChI: InChI=1S/C12H9BrO/c13-11-5-1-9(2-6-11)10-3-7-12(14)8-4-10/h1-8,14H
• InChIKey: ARUBXNBYMCVENE-UHFFFAOYSA-N
• SMILES: C1(C2=CC=C(Br)C=C2)=CC=C(O)C=C1
• CAS DataBase Reference: 29558-77-8(CAS DataBase Reference)

Description and Uses

A biphenyl starting material. 4-Bromo-(1,1-biphenyl)-4-ol is a useful intermediate. Vinylation of 4-bromo-4-hydroxybiphenyl and ethyl acrylate using Pd (OAc) 2/PPh 3 catalyst was studied. Ethyl 4-(4-hydroxyphenyl) cinnamate was formed as the vinylation product, while, 4-hydroxybiphenyl and ethyl cinnamate were formed as side products. Preparation of 4-cyano-4'-hydroxybiphenyl This was prepared from 4-bromo-4'-benzenesulphonyloxybiphenyl by first hydrolysing it to 4-bromo-4-hydroxybiphenyl using sodium hydroxide dissolved in a mixture of water and dioxan. The syntheses of the Nanocomposite dendrimers based on cyclic phosphazene cores: Amorphous materials, were accomplished by following a modified literature procedure by reacting phosphonitrilic chloride trimer with 4-bromophenol or 4-bromo-4-hydroxybiphenyl, respectively, in the presence of K 2 CO 3 in tetrahydrofuran (THF).

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P280a-P304+P340-P405-P501a-P261-P305+P351+P338
• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• HS Code: 29081990