A1417712
Borane dimethyl sulfide complex , 2.0MsolutioninTHF , 13292-87-0
Synonym(s):
(Dimethyl sulfide)trihydroboron;BMS;Borane-dimethyl sulfide;Trihydro[thiobis[methane]]boron
CAS NO.：13292-87-0
Empirical Formula: C2H10BS
Molecular Weight: 76.97
MDL number: MFCD00013189
EINECS: 236-313-6
| Pack Size | Price | Stock | Quantity |
| 100ML | RMB141.60 | In Stock |
|
| 1L | RMB439.20 | In Stock |
|
| 500ML | RMB469.60 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | -40--37°C |
| Boiling point: | ~34 °C |
| Density | 1.287 g/mL at 25 °C |
| refractive index | 1.4570 |
| Flash point: | 65 °F |
| storage temp. | 2-8°C |
| solubility | Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents. |
| form | Solution |
| color | Colorless to pale yellow |
| Specific Gravity | 0.801 |
| Water Solubility | reacts |
| Sensitive | Air & Moisture Sensitive |
| BRN | 3663489 |
| InChIKey | RMHDLBZYPISZOI-UHFFFAOYSA-N |
| CAS DataBase Reference | 13292-87-0(CAS DataBase Reference) |
| NIST Chemistry Reference | Borane-methyl sulfide complex(13292-87-0) |
| EPA Substance Registry System | Boron, trihydro[thiobis[methane]]-, (T-4)- (13292-87-0) |
Description and Uses
Borane-dimethyl sulfide (BH3 Me2S) can be used as a reagent:
- For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate.
- For the conversion of ozonides to alcohols.
- In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols.
- For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C3-symmetric tripodal hydroxyamide as a ligand.
- For the hydroboration reduction and other applications.
- With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.
Safety
| Symbol(GHS) |     GHS02,GHS05,GHS06,GHS08 |
| Signal word | Danger |
| Hazard statements | H225-H260-H301+H311-H318-H360FD-H412 |
| Precautionary statements | P210-P231+P232-P273-P280-P301+P310-P305+P351+P338 |
| Hazard Codes | F+,Xn,F,Xi |
| Risk Statements | 12-14/15-19-20/22-37/38-41-67-65-63-48/20-38-11-22-14-40-36-21-36/37/38-37 |
| Safety Statements | 36/37-62-36/39-33-26-23-16-36-24/25-7/8-43-39-36/37/39 |
| RIDADR | UN 3399 4.3/PG 1 |
| WGK Germany | 3 |
| RTECS | PV5080000 |
| F | 10-13-23 |
| TSCA | Yes |
| HazardClass | 4.3 |
| PackingGroup | II |
| HS Code | 29309090 |
| Excepted Quantities | Not Permitted as Excepted Quantity |
