2-Bromoacetophenone , Used for GC derivatives, ≥99.0% , 70-11-1

Synonym(s):
ω-Bromoacetophenone;2-Bromoacetophenone;Phenacyl bromide;Phenacyl bromide, ω-Bromoacetophenone

CAS NO.：70-11-1

Empirical Formula: C8H7BrO

Molecular Weight: 199.04

MDL number: MFCD00000195

EINECS: 200-724-9

Update time: 2022-07-08

PRODUCT Properties

Melting point:	48-51 °C (lit.)
Boiling point:	135 °C/18 mmHg (lit.)
Density	1.476
refractive index	1.5700 (estimate)
Flash point:	>230 °F
storage temp.	2-8°C
solubility	Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form	Crystals or Powder
color	White to dark green-brown
Water Solubility	PRACTICALLY INSOLUBLE
Merck	14,1402
BRN	606474
Stability:	Stable. Incompatible with strong bases, strong oxidizing agents. Combustible.
InChI	1S/C8H7BrO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2
InChIKey	LIGACIXOYTUXAW-UHFFFAOYSA-N
SMILES	BrCC(=O)c1ccccc1
CAS DataBase Reference	70-11-1(CAS DataBase Reference)
NIST Chemistry Reference	Ethanone, 2-bromo-1-phenyl-(70-11-1)
EPA Substance Registry System	Ethanone, 2-bromo-1-phenyl- (70-11-1)

Description and Uses

It is used in preparation of crystalline esters from acids. 2-Bromoacetophenone is a complete and irreversible inactivator of human liver aldehyde dehydrogenase isoenzymes E1 and E2.

Safety

Symbol(GHS)	GHS05
Signal word	Danger
Hazard statements	H314
Precautionary statements	P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
PPE	Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes	C
Risk Statements	34-20/21/22
Safety Statements	26-36/37/39-45
RIDADR	UN 2645 6.1/PG 2
WGK Germany	3
F	8-19
Hazard Note	Corrosive
TSCA	TSCA listed
HazardClass	6.1
PackingGroup	II
HS Code	29143990
Storage Class	6.1A - Combustible acute toxic Cat. 1 and 2 very toxic hazardous materials
Hazard Classifications	Skin Corr. 1B
Limited Quantities	100ml (liquid) or 0.5 Kg (solid)
Excepted Quantities	Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml)