(1S)-(-)-Camphanic chloride , 98% , 39637-74-6

Synonym(s):
(−)-Camphanoyl chloride;(1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride

CAS NO.：39637-74-6

Empirical Formula: C10H13ClO3

Molecular Weight: 216.66

MDL number: MFCD00135626

EINECS: 254-552-4

PRODUCT Properties

• Melting point: 71-73 °C(lit.)
• alpha: -18 º (c=2, CCl4)
• Boiling point: 310.92°C (rough estimate)
• Density: 1.2072 (rough estimate)
• refractive index: 1.5390 (estimate)
• storage temp.: 2-8°C
• solubility: soluble in Dichloromethane, Ether, Ethyl Acetate, Methanol
• form: Powder
• color: Yellow to orange-brown
• optical activity: [α]23/D 18°, c = 2 in carbon tetrachloride
• Water Solubility: decomposes
• Sensitive: Moisture Sensitive
• BRN: 3590860
• InChIKey: PAXWODJTHKJQDZ-RGURZIINSA-N
• CAS DataBase Reference: 39637-74-6(CAS DataBase Reference)

Description and Uses

(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.

Safety

• Symbol(GHS): GHS05
• Signal word: Danger
• Hazard statements: H314
• Precautionary statements: P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
• Hazard Codes: C,Xi
• Risk Statements: 34-29
• Safety Statements: 26-36/37/39-45-8-27
• RIDADR: UN 3261 8/PG 2
• WGK Germany: 3
• F: 10-21
• HazardClass: 8
• PackingGroup: II
• HS Code: 29322090
• Limited Quantities: 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)