Diisopropyl azodicarboxylate , 95% , 2446-83-5

Synonym(s):
DIAD;Diisopropyl azodiformate;Diisopropylazodicarboxylate

CAS NO.：2446-83-5

Empirical Formula: C8H14N2O4

Molecular Weight: 202.21

MDL number: MFCD00008875

EINECS: 219-502-8

PRODUCT Properties

• Melting point: 3-5 °C
• Boiling point: 75 °C/0.25 mmHg (lit.)
• Density: 1.027 g/mL at 25 °C (lit.)
• vapor pressure: 1.04 hPa (20 °C)
• refractive index: n20/D 1.420(lit.)
• Flash point: 223 °F
• storage temp.: Store below +30°C.
• solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
• form: Liquid
• color: Clear to slightly turbid yellow-orange to red
• Water Solubility: insoluble
• Sensitive: Light Sensitive
• BRN: 1912326
• InChI: InChI=1S/C8H14N2O4/c1-5(2)13-7(11)9-10-8(12)14-6(3)4/h5-6H,1-4H3
• InChIKey: VVWRJUBEIPHGQF-UHFFFAOYSA-N
• SMILES: N(C(OC(C)C)=O)=NC(OC(C)C)=O
• CAS DataBase Reference: 2446-83-5(CAS DataBase Reference)

Description and Uses

Diisopropyl azodicarboxylate is used as an important reagent in the production of many organic compounds. It is used in association with triphenyl phosphine in Mitsunobu reaction of alcohols, acids and amides. It acts as reactant in the preparation of chromenes resembling classical cannabinoids, norbornene-based guanidine-rich polymers and acceptor-donor-acceptor organic dyes.

Safety

• Symbol(GHS): GHS07,GHS08,GHS09
• Signal word: Warning
• Hazard statements: H315-H319-H335-H351-H411
• Precautionary statements: P202-P261-P273-P302+P352-P305+P351+P338-P308+P313
• Hazard Codes: Xn,Xi,N,F
• Risk Statements: 36/38-51/53-5-43-36/37/38-11-48/20/22-40
• Safety Statements: 36-61-47A-36/37/39-29-26-16-60-36/37
• RIDADR: UN 3082 9/PG 3
• WGK Germany: 1
• F: 4.10-8
• Hazard Note: Harmful/Irritant
• HazardClass: 9
• PackingGroup: III
• HS Code: 29270000