Home Categories Chemical Reagents Diethyl2-bromo-2-methylmalonate
A3388312

Diethyl2-bromo-2-methylmalonate , 98% , 29263-94-3

CAS NO.:29263-94-3

Empirical Formula: C8H13BrO4

Molecular Weight: 253.09

MDL number: MFCD00009125

EINECS: 249-541-6

Pack Size Price Stock Quantity
5G RMB79.20 In Stock
25G RMB220.80 In Stock
100G RMB652.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 105-106 °C (5 mmHg)
Density  1.325 g/mL at 25 °C (lit.)
refractive index  n20/D 1.449(lit.)
Flash point: >230 °F
storage temp.  Inert atmosphere,Room Temperature
form  clear liquid
color  Colorless to Almost colorless
BRN  1779673
InChI 1S/C8H13BrO4/c1-4-12-6(10)8(3,9)7(11)13-5-2/h4-5H2,1-3H3
InChIKey CSLQAXTUGPUBCW-UHFFFAOYSA-N
SMILES CCOC(=O)C(C)(Br)C(=O)OCC
CAS DataBase Reference 29263-94-3(CAS DataBase Reference)

Description and Uses

Diethyl 2-bromo-2-methylmalonate was used to investigate the 1,2,2,6,6-pentamethylpiperidine as an effective reducing agent for the radical chain conversion of primary bromoesters to the corresponding esters. It was used in the synthesis of polystyrene macroinitiator via atom transfer radical polymerization.

Safety

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  C
Risk Statements  34-20/21/22
Safety Statements  26-36/37/39-45
RIDADR  UN 3265 8/PG 2
WGK Germany  3
HS Code  2917.19.7050
HazardClass  8
PackingGroup  III
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Eye Dam. 1
Skin Corr. 1B
Limited Quantities 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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