DIBUTYLBORON TRIFLUOROMETHANESULFONATE , 0.7mol/Lindiethylether,Energyseal , 60669-69-4

Synonym(s):
Dibutylboron triflate solution

Update time: 2022-07-08

Boiling point:	37℃ (0.12 Torr)
Density	1.271 g/mL at 25 °C
Flash point:	80 °F
storage temp.	2-8°C
form	Solution
color	Clear light yellow to orange
BRN	1968660
InChI	InChI=1S/C9H18BF3O3S/c1-3-5-7-10(8-6-4-2)16-17(14,15)9(11,12)13/h3-8H2,1-2H3
InChIKey	FAVAVMFXAKZTMV-UHFFFAOYSA-N
SMILES	B(CCCC)(CCCC)OS(=O)(=O)C(F)(F)F

Dibutylboryl trifluoromethanesulfonate may be used in the following studies:

Stereo- and regio-selective synthesis of erythro aldols.
As a promoter for the solution and polymer-supported trichloroacetimidate-based glycosylations.
Synthesis of β-alkoxy carbonyl compounds via one-step Mukaiyama aldol-type reaction.
Aldol-type cyclization for the stereoselective synthesis of cyclic ethers.
As a reagent for the formation of boron enolates.
As a complexation aid for the isolation of 1-acyldipyrromethanes.
As a promoter in [1,2]-Wittig reaction between aldehydes and O-benzyl or O-allyl glycolate esters, creating two contiguous stereocenters (1,2-diol) in good yield without the need for strong base.