Dichlorotetrakis(triphenylphosphine)ruthenium(II) , 95% , 15555-77-8

Synonym(s):
Dichlorotris(triphenylphosphine)ruthenium(II);Ruthenium(II)-tris(triphenylphosphine) dichloride;Tris(triphenylphosphine)dichlororuthenium

CAS NO.：15555-77-8

Empirical Formula: C54H45Cl2P3Ru

Molecular Weight: 958.83

MDL number: MFCD00013077

EINECS: 624-278-3

PRODUCT Properties

• Melting point: 159 °C
• storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Appearance: Brown to reddish brown Solid
• InChI: 1S/4C18H15P.2ClH.Ru/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h4*1-15H;2*1H;/q;;;;;;+2/p-2
• InChIKey: OIWNHEPSSHYXTG-UHFFFAOYSA-L
• SMILES: Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
• CAS DataBase Reference: 15555-77-8(CAS DataBase Reference)

Description and Uses

Catalyst for:

• Selective hydrogenation of maleic anhydride or succinic anhydride
• Sythesis of portions of the natural antibiotic tetrodecamycin
• Oxidation of hydroxamic acid
• Hydroesterification reactions
• Hydroboration of alkenes
• Oxidation of sulfide

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H302+H312+H332
• Precautionary statements: P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
• PPE: dust mask type N95 (US), Eyeshields, Gloves
• Hazard Codes: Xn
• Risk Statements: 20/21/22
• Safety Statements: 36/37-36
• WGK Germany: 3
• Storage Class: 11 - Combustible Solids
• Hazard Classifications: Acute Tox. 4 Dermal; Acute Tox. 4 Inhalation; Acute Tox. 4 Oral