Home Categories Chemical Reagents Methanol-12C,d4
A5359212

Methanol-12C,d4 , D,99.8%(0.05%v/vTMS) , 811-98-3

Synonym(s):
Methanol-D4;Methyl-d3 alcohol d;Tetradeuteromethanol

CAS NO.:811-98-3

Empirical Formula: CD4O

Molecular Weight: 36.07

MDL number: MFCD00044637

EINECS: 212-378-6

Pack Size Price Stock Quantity
5g RMB120.00 In Stock
2×0.6ml RMB127.20 In Stock
10×0.6ML RMB319.20 In Stock
10G RMB399.20 In Stock
25G RMB959.20 In Stock
50g RMB1599.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: -99 °C
Melting point: -97,8°C
Boiling point: 65.4 °C(lit.)
Boiling point: 64,7°C
Density  0.888 g/mL at 25 °C(lit.)
Density  d = 0,89
vapor pressure  129 hPa (20 °C)
refractive index  n20/D 1.326(lit.)
Flash point: 52 °F
storage temp.  no restrictions.
solubility  Chloroform (Slightly), Water (Slightly)
form  Liquid
color  Colorless
Specific Gravity 0.89
explosive limit 5.5-36.5%(V)
Water Solubility  Miscible with water, ethanol, ether, acetone and chloroform.
BRN  1733278
Exposure limits ACGIH: TWA 200 ppm; STEL 250 ppm (Skin)
OSHA: TWA 200 ppm(260 mg/m3)
NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3)
Stability: Stable. Incompatible with moisture, acids, acid chlorides, acid anhydrides, oxidizing agents, reducing agents, alkali metals. Highly flammable.
InChI 1S/CH4O/c1-2/h2H,1H3/i1D3,2D
InChIKey OKKJLVBELUTLKV-MZCSYVLQSA-N
SMILES [2H]OC([2H])([2H])[2H]
CAS DataBase Reference 811-98-3(CAS DataBase Reference)
EPA Substance Registry System Methanol-d4 (811-98-3)
CAS Number Unlabeled 67-56-1

Description and Uses

Methanol-d4 may be used as a solvent to analyze the rate of exchange of methoxyl group in camphor and norcamphor dimethyl ketals.

Safety

Symbol(GHS)  Flame (GHS02)Skull and Crossbones (GHS06)Health Hazard (GHS08)
GHS02,GHS06,GHS08
Signal word  Danger
Hazard statements  H225-H301+H311+H331-H370
Precautionary statements  P210-P233-P280-P301+P310-P303+P361+P353-P304+P340+P311
target organs Eyes,Central nervous system
Hazard Codes  F,T
Risk Statements  11-23/24/25-39/23/24/25
Safety Statements  7-16-36/37-45
RIDADR  UN 1230 3/PG 2
WGK Germany  1
RTECS  PC1400000
10-21
Autoignition Temperature 440 °C
TSCA  TSCA listed
HazardClass  3
PackingGroup  II
HS Code  28459000
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Flam. Liq. 2
STOT SE 1
Toxicity LD50 orally in Rabbit: 5628 mg/kg LD50 dermal Rabbit 17100 mg/kg
Limited Quantities 1.0 L (0.3 gallon) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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