A5397212
Methyl bromoacetate , 97% , 96-32-2
Synonym(s):
Bromoacetic acid methyl ester;METHYL BROMOACETATE
CAS NO.：96-32-2
Empirical Formula: C3H5BrO2
Molecular Weight: 152.97
MDL number: MFCD00000189
EINECS: 202-499-2
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | -50°C |
| Boiling point: | 51-52 °C/15 mmHg (lit.) |
| Density | 1.616 g/mL at 25 °C (lit.) |
| vapor pressure | 18 hPa (50 °C) |
| refractive index | n |
| Flash point: | 145 °F |
| storage temp. | Store below +30°C. |
| form | Liquid |
| color | Clear colorless to slightly yellow |
| Specific Gravity | 1.416 |
| Water Solubility | Miscible with methanol, ether and acetone. Slightly miscible with water |
| FreezingPoint | <-50℃ |
| BRN | 506256 |
| LogP | 0.71 at 25℃ |
| CAS DataBase Reference | 96-32-2(CAS DataBase Reference) |
| NIST Chemistry Reference | Acetic acid, bromo-, methyl ester(96-32-2) |
| EPA Substance Registry System | Acetic acid, bromo-, methyl ester (96-32-2) |
Description and Uses
Methyl bromoacetate is used in the synthesis of coumarins and cis-cyclopropanes. It reacts with the conjugate base of (methylmethoxycarbene)pentacarbonylchromium(0) to prepare alkylated carbene complexes. Further, it is used to make vitamins and pharmaceuticals.
Safety
| Symbol(GHS) |   GHS05,GHS06 |
| Signal word | Danger |
| Hazard statements | H301-H314-H317-H335 |
| Precautionary statements | P261-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
| Hazard Codes | T,Xi,F |
| Risk Statements | 25-34-37-23/24/25-40-36/37/38-38 |
| Safety Statements | 26-36/37/39-45-28A-36-16 |
| RIDADR | UN 2643 6.1/PG 2 |
| WGK Germany | 3 |
| RTECS | AF6300000 |
| F | 19 |
| TSCA | Yes |
| HazardClass | 6.1 |
| PackingGroup | II |
| HS Code | 29159080 |
| Hazardous Substances Data | 96-32-2(Hazardous Substances Data) |
| Limited Quantities | 100ml (liquid) or 0.5 Kg (solid) |
| Excepted Quantities | Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml) |
