Methylmagnesium Bromide , 3.0Msolutionin2-Methyl-THF , 75-16-1

CAS NO.：75-16-1

Empirical Formula: CH3BrMg

Molecular Weight: 119.24

MDL number: MFCD00000041

EINECS: 200-844-1

PRODUCT Properties

• Boiling point: 78-80℃
• Density: 1.035 g/mL at 25 °C
• Flash point: 77 °F
• storage temp.: water-free area
• form: Solution, may develop some turbidity precipitate
• color: Pale brown
• Water Solubility: Reacts with water.
• Sensitive: Air & Moisture Sensitive
• BRN: 3535220
• InChI: InChI=1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1
• InChIKey: AVFUHBJCUUTGCD-UHFFFAOYSA-M
• SMILES: [Mg](C)Br
• CAS DataBase Reference: 75-16-1(CAS DataBase Reference)
• EPA Substance Registry System: Magnesium, bromomethyl- (75-16-1)

Description and Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

Safety

• Symbol(GHS): GHS02,GHS05,GHS07,GHS08
• Signal word: Danger
• Hazard statements: H302-H314-H371-H372-H351-H335-H224-H260
• Precautionary statements: P501-P223-P270-P202-P240-P231+P232-P260-P210-P233-P201-P243-P241-P242-P271-P264-P280-P370+P378-P335+P334-P308+P311-P303+P361+P353-P301+P330+P331-P363-P301+P312+P330-P304+P340+P310-P305+P351+P338+P310-P403+P233-P402+P404-P403+P235-P405
• target organs: Respiratory system
• PPE: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
• Hazard Codes: C,F+,F
• Risk Statements: 12-14-19-22-34-66-67-52/53-10-65-63-48/20-14/15-11-37
• Safety Statements: 9-16-26-45-61-36/37/39-62-43-36/37-23
• RIDADR: UN 1928
• WGK Germany: 2
• RTECS: OM3700000
• F: 1-3-10
• TSCA: TSCA listed
• HazardClass: 4.3
• PackingGroup: I
• HS Code: 29319090
• Storage Class: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• Hazard Classifications: Aquatic Chronic 3; Eye Dam. 1; Flam. Liq. 3; Skin Corr. 1B; STOT SE 3; Water-react 1
• Hazardous Substances Data: 75-16-1(Hazardous Substances Data)
• REACH Registrations: Active
• Excepted Quantities: Not Permitted as Excepted Quantity