Home Categories Organic Chemistry 2,6-Dimethylphenylmagnesium bromide
F518421

2,6-Dimethylphenylmagnesium bromide , Null , 21450-64-6

CAS NO.:21450-64-6

Empirical Formula: C8H9BrMg

Molecular Weight: 209.37

MDL number: MFCD00192083

Pack Size Price Stock Quantity
100ml RMB3459.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 65-67 °C
Density  0.998 g/mL at 25 °C
Flash point: −2 °F
form  Solution
color  Colorless to yellow-brown
Sensitive  Air & Moisture Sensitive
InChI 1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h3-5H,1-2H3;1H;/q;;+1/p-1
InChIKey BIGUVDUZGAJWQK-UHFFFAOYSA-M
SMILES Cc1cccc(C)c1[Mg]Br
CAS DataBase Reference 21450-64-6

Description and Uses

2,6-Dimethylphenylmagnesium bromide can be used:

  • As an intermediate in the synthesis of dibutyl(5,10-dihydro-1,9-di-p-toluoyl-5-p-tolyldipyrrinato)tin(IV), which is further used in the preparation of zinc-based porphyrin.
  • As a substrate in the preparation of substituted fluorenes by reacting with 2-substituted arenesulfonates and dihaloarenes.

Safety

Symbol(GHS) 
GHS02,GHS05,GHS06,GHS08
Signal word  Danger
Hazard statements  H318-H225-H261-H302-H314-H331-H335-H351
Precautionary statements  P260h-P303+P361+P353-P305+P351+P338-P405-P501a-P210-P231+P232-P280-P370+P378-P402+P404-P403+P235
target organs Respiratory system
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  F,C
Risk Statements  11-14-19-20/21/22-34-40-37-14/15
Safety Statements  16-23-26-36/37/39-45-43
RIDADR  UN 3399 4.3/PG 2
WGK Germany  3
HazardClass  3
Storage Class 4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications Acute Tox. 3 Inhalation
Acute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Water-react 2

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