Phenylmagnesium Bromide , 1.0MinTHF , 100-58-3

Synonym(s):
PhMgBr solution

CAS NO.：100-58-3

Empirical Formula: C6H5BrMg

Molecular Weight: 181.31

MDL number: MFCD00000038

EINECS: 202-867-2

PRODUCT Properties

• Melting point: 153-154 °C
• Density: 1.134 g/mL at 25 °C
• Flash point: −40 °F
• storage temp.: water-free area
• solubility: Miscible with tetrahydrofuran.
• form: Liquid
• color: Yellow to brown
• Specific Gravity: 1.14
• Appearance: Clear to slightly hazy colorless to dark brown liquid.
• Water Solubility: reacts
• Sensitive: Air & Moisture Sensitive
• BRN: 3588849
• InChI: InChI=1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
• InChIKey: ANRQGKOBLBYXFM-UHFFFAOYSA-M
• SMILES: C1([Mg]Br)C=CC=CC=1
• CAS DataBase Reference: 100-58-3(CAS DataBase Reference)
• EPA Substance Registry System: Magnesium, bromophenyl- (100-58-3)

Description and Uses

These compounds can be obtained as a formula ``RMgX'' by the reaction of halogenated hydrocarbons with magnesium metal in anhydrous solvents such as diethyl ether, and have been widely used in organic synthesis.
Grignard reagent in greener solvent, 2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Safety

• Symbol(GHS): GHS02,GHS05,GHS07
• Signal word: Danger
• Hazard statements: H225-H302-H314
• Precautionary statements: P210-P233-P280-P301+P312-P303+P361+P353-P305+P351+P338
• Hazard Codes: F+,C,F
• Risk Statements: 12-14-22-34-19-11-67-40-37
• Safety Statements: 16-26-36/37/39-45-33-29-7/8-6A-43B
• RIDADR: UN 3399 4.3/PG 1
• WGK Germany: 1
• F: 1-3-10
• TSCA: Yes
• HazardClass: 4.3
• PackingGroup: II
• HS Code: 29319090
• Hazardous Substances Data: 100-58-3(Hazardous Substances Data)