Pirimicarb solution , analyticalstandard,10μg/mlinacetone , 23103-98-2

Synonym(s):
2-Dimethylamino-5,6-dimethyl-4-pyrimidinyl dimethylcarbamate

CAS NO.：23103-98-2

Empirical Formula: C11H18N4O2

Molecular Weight: 238.29

MDL number: MFCD00055520

EINECS: 245-430-1

PRODUCT Properties

• Melting point: 90.5°C
• Boiling point: 380.88°C (rough estimate)
• Density: 1.1387 (rough estimate)
• vapor pressure: 2.1 x 10^-3 Pa (30 °C)
• refractive index: 1.6081 (estimate)
• Flash point: >100 °C
• storage temp.: APPROX 4°C
• solubility: Acetone (Slightly), Chloroform (Slightly), Methanol (Slightly)
• Water Solubility: 3060 mg l^-1
• pka: 4.34 (weak base)
• form: Solid
• color: White to off-white
• Merck: 13,7579
• BRN: 663442
• Henry's Law Constant: 1.2×10⁴ mol/(m³Pa) at 25℃, HSDB (2015)
• Major Application: agriculture; environmental
• InChI: 1S/C11H18N4O2/c1-7-8(2)12-10(14(3)4)13-9(7)17-11(16)15(5)6/h1-6H3
• InChIKey: YFGYUFNIOHWBOB-UHFFFAOYSA-N
• SMILES: CN(C)C(=O)Oc1nc(nc(C)c1C)N(C)C
• LogP: 1.700
• CAS DataBase Reference: 23103-98-2(CAS DataBase Reference)
• NIST Chemistry Reference: Pirimicarb(23103-98-2)
• EPA Substance Registry System: Pirimicarb (23103-98-2)

Description and Uses

Pirimicarb is a colorless solid that is moderately soluble in water, acetone, ethanol, xylene, and chloroform.
Pirimicarb is produced by reaction of 2-dimethylamino- 5,6-dimethyl-4-pyrimidone with dimethylcarbamic acid chloride in the presence of a base or phosgene and dimethylamine. Pirimicarb is a systemic, selective aphicide used largely on grain crops, but also on ornamentals, cotton, fruit, and in greenhouses.

Insecticide.

Safety

• Symbol(GHS): GHS06,GHS08,GHS09
• Signal word: Danger
• Hazard statements: H301+H331-H317-H351-H410
• Precautionary statements: P202-P273-P280-P301+P310-P302+P352-P304+P340+P311
• PPE: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• Hazard Codes: T;N,N,T,Xn,F
• Risk Statements: 25-50/53-36-20/21/22-11
• Safety Statements: 22-37-45-60-61-36-26-16-36/37
• RIDADR: UN 2811
• WGK Germany: 3
• RTECS: EZ9100000
• HazardClass: 6.1(b)
• PackingGroup: III
• Storage Class: 6.1C - Combustible, acute toxic Cat.3; toxic compounds or compounds which causing chronic effects
• Hazard Classifications: Acute Tox. 3 Inhalation; Acute Tox. 3 Oral; Aquatic Acute 1; Aquatic Chronic 1; Carc. 2; Skin Sens. 1
• Hazardous Substances Data: 23103-98-2(Hazardous Substances Data)
• Toxicity: LD50 orally in female rats: 147 (mg/kg) (Baranyovits, Ghosh)