A6909012
Phenyl Trifluoromethanesulfonate , >98.0%(GC) , 17763-67-6
Synonym(s):
Phenyl triflate
| Pack Size | Price | Stock | Quantity |
| 1G | RMB63.20 | In Stock |
|
| 5G | RMB224.80 | In Stock |
|
| 25g | RMB847.20 | In Stock |
|
| 100g | RMB2719.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Boiling point: | 99-100 °C/60 mmHg (lit.) |
| Density | 1.396 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 160 °F |
| storage temp. | Inert atmosphere,Room Temperature |
| form | clear liquid |
| color | Colorless to Almost colorless |
| InChI | InChI=1S/C7H5F3O3S/c8-7(9,10)14(11,12)13-6-4-2-1-3-5-6/h1-5H |
| InChIKey | GRJHONXDTNBDTC-UHFFFAOYSA-N |
| SMILES | C(F)(F)(F)S(OC1=CC=CC=C1)(=O)=O |
Description and Uses
Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies:
As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos.
As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling.
Synthesis of N-(2,6-diarylbenzoyl)anilines by diarylation of benzanilides with phenyl triflate in the presence of palladium-based catalyst.
As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofuran by the arylation of 2,3-dihydrofuran.
Safety
| Symbol(GHS) |   GHS05,GHS06 |
| Signal word | Danger |
| Hazard statements | H301+H311-H314 |
| Precautionary statements | P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P361+P364 |
| Hazard Codes | T |
| Risk Statements | 36/37/38-34-24/25 |
| Safety Statements | 26-36-45-36/37/39 |
| RIDADR | UN 2927 6.1/PG 2 |
| WGK Germany | 3 |
| HazardClass | 6.1, 8 |
| HS Code | 29049090 |
| Limited Quantities | 100ml (liquid) or 0.5 Kg (solid) |
| Excepted Quantities | Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml) |
