(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde , 95% , 15186-48-8

Synonym(s):
(R)-(+)-Glyceraldehyde acetonide;(R)-Isopropylideneglyceraldehyde;NSC 89869

CAS NO.：15186-48-8

Empirical Formula: C6H10O3

Molecular Weight: 130.14

MDL number: MFCD00269682

EINECS: 676-289-8

PRODUCT Properties

• alpha: 53.8 º (c=2, CHCl3)
• Boiling point: 139 °C (lit.)
• Density: 1.045 g/mL at 25 °C (lit.)
• refractive index: n20/D 1.454(lit.)
• Flash point: 143 °F
• storage temp.: -20°C
• solubility: Difficult to mix.
• form: Liquid
• color: Colorless to Pale Yellow
• optical activity: [α]22/D +53.8°, c = 2 in chloroform
• InChI: InChI=1S/C6H10O3/c1-6(2)8-4-5(3-7)9-6/h3,5H,4H2,1-2H3/t5-/m0/s1
• InChIKey: YSGPYVWACGYQDJ-YFKPBYRVSA-N
• SMILES: O1C[C@H](C=O)OC1(C)C
• CAS DataBase Reference: 15186-48-8(CAS DataBase Reference)
• NIST Chemistry Reference: Acetone D-glyceraldehyde(15186-48-8)

Description and Uses

Reactant involved in organic reactions including:

• Henry condensation reactions
• Synthesis of highly functionalized chiral aziridines
• Olefination of aldehydes
• C-H oxidations
• Aldol-type condensations
• Synthesis of hydrophilic pyrazine dyes for use as exogenous fluorescent tracer agents
• Hosomi-Sakurai reactions

Safety

• Symbol(GHS): GHS08
• Signal word: Danger
• Hazard statements: H227-H303-H333-H351
• Precautionary statements: P201-P210e-P280-P403+P235-P405-P501a
• WGK Germany: 3
• HazardClass: 6.1
• HS Code: 29329990