(1<i>R</i>)-(-)-Camphorquinone , >98.0%(GC) , 10334-26-6

Synonym(s):
(1R)-(−)-2,3-Bornanedione;2,3-Bornanedione

CAS NO.：10334-26-6

Empirical Formula: C10H14O2

Molecular Weight: 166.22

MDL number: MFCD00082863

EINECS: 626-988-9

PRODUCT Properties

• Melting point: 200-203 °C(lit.)
• alpha: -101° (20/D)(c=2, C6H5CH3)
• Boiling point: 254.44°C (rough estimate)
• Density: 1.0060 (rough estimate)
• refractive index: 1.5200 (estimate)
• storage temp.: Sealed in dry,Room Temperature
• solubility: almost transparency in Methanol
• form: powder to crystal
• color: Light yellow to Yellow
• optical activity: [α]20/D 101°, c = 2 in toluene
• BRN: 2327696
• InChI: InChI=1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10+/m1/s1
• InChIKey: VNQXSTWCDUXYEZ-LDWIPMOCSA-N
• SMILES: [C@]12(C)C(C)(C)[C@]([H])(CC1)C(=O)C2=O
• CAS DataBase Reference: 10334-26-6(CAS DataBase Reference)

Description and Uses

(1R)-()-Camphorquinone can be used as a chiral starting material for the preparation of:

• α-Hydroxycamphors by selective reduction of keto groups using various vegetables.
• Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies.
• Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents.
• Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.

Safety

• Symbol(GHS): GHS07,GHS08
• Signal word: Danger
• Hazard statements: H302-H334
• Precautionary statements: P301+P312+P330
• PPE: dust mask type N95 (US), Eyeshields, Faceshields, Gloves
• Hazard Codes: Xn
• Risk Statements: 22-43
• Safety Statements: 36/37
• WGK Germany: 3
• HS Code: 2914.29.5000
• Storage Class: 11 - Combustible Solids
• Hazard Classifications: Acute Tox. 4 Oral; Resp. Sens. 1