(+)-(S)-N,N-Dimethyl-1-[(R)-1′,2-bis(diphenylphosphino)ferro , 95% , 55650-59-4

CAS NO.：55650-59-4

Empirical Formula: C38H37FeNP210*

Molecular Weight: 625.5

MDL number: MFCD00075283

PRODUCT Properties

• Melting point: 138-142 °C(lit.)
• storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• form: solid
• color: Light yellow to Brown
• optical activity: [α]20/D +350°, c = 0.5 in chloroform
• InChIKey: VUJPTJYMSBMZOZ-RMRYJAPISA-N
• SMILES: [Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.C[C@@H]([C]4[CH][CH][CH][C]4P(c5ccccc5)c6ccccc6)N(C)C

Description and Uses

Ligand used in the asymmetric hydrogenation of (Z)-α-amido-cinnamic acids

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H302-H312-H315-H319-H332-H335-H302+H312+H332
• Precautionary statements: P264-P270-P271-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501-P261-P280-P305+P351+P338
• target organs: Respiratory system
• PPE: dust mask type N95 (US), Eyeshields, Gloves
• Hazard Codes: Xn
• Risk Statements: 20/21/22-36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• HS Code: 29319090
• Storage Class: 11 - Combustible Solids
• Hazard Classifications: Acute Tox. 4 Dermal; Acute Tox. 4 Inhalation; Acute Tox. 4 Oral; Eye Irrit. 2; Skin Irrit. 2; STOT SE 3