A7540312
Sodium thiophenolate , 90% , 930-69-8
Synonym(s):
Benzenethiol sodium salt;Sodium thiophenoxide;Thiophenol sodium salt
CAS NO.：930-69-8
Empirical Formula: C6H7NaS
Molecular Weight: 134.17
MDL number: MFCD00066460
EINECS: 213-224-0
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | >300 °C (lit.) |
| solubility | DMSO (Slightly), Methanol (Slightly, Sonicated) |
| form | Powder |
| color | Off-white to yellow to beige |
| Hydrolytic Sensitivity | 0: forms stable aqueous solutions |
| BRN | 3597302 |
| Stability: | Hygroscopic |
| EPA Substance Registry System | Benzenethiol, sodium salt (930-69-8) |
Description and Uses
Sodium thiophenolate has been used for the synthesis of MCoTI-I and MCoTI-II cyclotides, which are naturally-occurring cyclic cystine-knot microprotein trypsin inhibitors. It may be employed in the following studies:
- As probe for the immunoassay and for the detection of label-free protein by surface-enhanced Raman scattering (SERS).
- Preparation of new cyclometalated 6-phenyl-4-(p-R-phenyl)-2,2′-bipyridyl (C--N--N)Pt(II) thiophenolate complexes.
- Synthesis of 1,3,5,7,9-pentakis(4-methoxyphenylthio)corannulene, 1,3,5,7,9-pentakis(2-naphthylthio)corannulene and 1,3,6,8-tetrakis(4-methoxyphenylthio)corannulene.
- Synthesis of Et4N+ salts of homoleptic arylthiolate Ti(IV) complex, [Ti(SPh)6]2-.
Safety
| Symbol(GHS) |  GHS05 |
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 1759 8/PG 3 |
| WGK Germany | 3 |
| F | 1-10-13 |
| TSCA | No |
| HazardClass | 6.1(b) |
| PackingGroup | III |
| HS Code | 29309090 |
| Hazardous Substances Data | 930-69-8(Hazardous Substances Data) |
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) |
