Tris(2-aminoethyl)amine , 96% , 4097-89-6

Synonym(s):
2,2′,2′′-Nitrilotriethylamine;2,2′,2′′-Triaminotriethylamine;TAEA

CAS NO.：4097-89-6

Empirical Formula: C6H18N4

Molecular Weight: 146.23

MDL number: MFCD00008177

EINECS: 223-857-4

PRODUCT Properties

• Melting point: -16 °C
• Boiling point: 114 °C/15 mmHg (lit.)
• Density: 0.976 g/mL at 20 °C (lit.)
• vapor density: 5 (vs air)
• vapor pressure: 0.02 mm Hg ( 20 °C)
• refractive index: n20/D 1.497(lit.)
• Flash point: >230 °F
• storage temp.: 2-8°C
• solubility: Chloroform (Sparingly), DMSO (Slightly)
• form: saline suspension
• pka: 10.00±0.10(Predicted)
• color: Clear yellow
• Specific Gravity: 0.977
• Water Solubility: Miscible with water.
• Sensitive: Hygroscopic
• BRN: 1739626
• Stability: Stable. Hygroscopic. Absorbs carbon dioxide from the air. Incompatible with strong acids, strong oxidizing agents.
• CAS DataBase Reference: 4097-89-6(CAS DataBase Reference)
• EPA Substance Registry System: 1,2-Ethanediamine, N,N-bis(2-aminoethyl)- (4097-89-6)

Description and Uses

Tris(2-aminoethyl)amine is a tetradentate chelating ligand and forms stable complexes with transition metals. It is also used as a carbon dioxide absorbent. Further, it acts as a reagent for cleavage of the fluorenylmethyloxycarbonyl (Fmoc) group in peptide synthesis. It reacts with aryl isocyanates and isothiocyanates to give tris-urea and -thiourea derivatives.

Safety

• Symbol(GHS): GHS05,GHS06
• Signal word: Danger
• Hazard statements: H301-H310-H314
• Precautionary statements: P270-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338
• Hazard Codes: T,Xi
• Risk Statements: 22-24-34-36/37/38-10
• Safety Statements: 26-36/37/39-45-16
• RIDADR: UN 2922 8/PG 2
• WGK Germany: 3
• RTECS: KH8587082
• F: 3-10-23
• TSCA: Yes
• HazardClass: 6.1
• PackingGroup: II
• HS Code: 29211990
• Toxicity: mouse,LD50,oral,1800mg/kg (1800mg/kg),LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSIONBEHAVIORAL: ATAXIAGASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA","Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 223, 1999.
• Limited Quantities: 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)