Tris(4-carbazoyl-9-ylphenyl)amine , 98% , 139092-78-7

Synonym(s):
TCTA

CAS NO.：139092-78-7

Empirical Formula: C54H36N4

Molecular Weight: 740.89

MDL number: MFCD03093250

EINECS: 625-738-6

PRODUCT Properties

• Melting point: 298~300°C
• Density: 1.23±0.1 g/cm3(Predicted)
• storage temp.: Inert atmosphere,Room Temperature
• solubility: THF: soluble; chloroform: soluble; dichloromethane: soluble
• form: powder to crystal
• pka: -5.97±0.60(Predicted)
• color: White to Orange to Green
• λmax: 326nm(CH2Cl2)(lit.)
• InChIKey: AWXGSYPUMWKTBR-UHFFFAOYSA-N
• SMILES: C1(N(C2=CC=C(N3C4=C(C=CC=C4)C4=C3C=CC=C4)C=C2)C2=CC=C(N3C4=C(C=CC=C4)C4=C3C=CC=C4)C=C2)=CC=C(N2C3=C(C=CC=C3)C3=C2C=CC=C3)C=C1
• CAS DataBase Reference: 139092-78-7
• Absorption: λmax?293?and?326 nm (THF)

Description and Uses

Having three carbazole units as the pendants and triarylamine at the core,?tris(4-carbazoyl-9-ylphenyl)amine (TCTA) is electron-rich. As a result, it is widely used as a hole-transport and hole-injection material in light-emitting diodes and perovskite solar cells. With low electron mobility, TCTA has also been used as exciton/electron blocking layer materials because of its high lying LUMO energy level (LUMO = 2.4 eV).

4,4'',4''''-Tris(carbazol-9-yl)-triphenylamine has been patented for use in the preparation of light-emitting materials for organic electroluminescent devices.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P264-P271-P280-P302+P352-P305+P351+P338
• target organs: Respiratory system
• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26-36/37-36
• WGK Germany: 3
• HS Code: 29339900
• Storage Class: 11 - Combustible Solids
• Hazard Classifications: Eye Irrit. 2; Skin Irrit. 2; STOT SE 3