A7871512
Tris(2,6-dimethoxyphenyl)phosphine , >97.0%(HPLC) , 85417-41-0
Synonym(s):
DMPP
| Pack Size | Price | Stock | Quantity |
| 1g | RMB68.00 | In Stock |
|
| 5g | RMB192.00 | In Stock |
|
| 25G | RMB528.00 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 145-147 °C(lit.) |
| Boiling point: | 566.4±50.0 °C(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | very faint turbidity in hot Methanol |
| form | Powder |
| color | white to off-white |
| Sensitive | air sensitive |
| InChI | 1S/C24H27O6P/c1-25-16-10-7-11-17(26-2)22(16)31(23-18(27-3)12-8-13-19(23)28-4)24-20(29-5)14-9-15-21(24)30-6/h7-15H,1-6H3 |
| InChIKey | CMLWFCUAXGSMBB-UHFFFAOYSA-N |
| SMILES | COc1cccc(OC)c1P(c2c(OC)cccc2OC)c3c(OC)cccc3OC |
| CAS DataBase Reference | 85417-41-0 |
Description and Uses
Catalyst for:
- Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
- Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
- Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
- Oxycylizations of allendiols
- Enantioselective aldol reactions
- Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P280a-P304+P340-P405-P501a-P261-P305+P351+P338 |
| target organs | Respiratory system |
| PPE | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 29310099 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
