Home Categories 2,4,6-TRIPHENYLPYRIDINE
A8408712

2,4,6-TRIPHENYLPYRIDINE , 98% , 580-35-8

CAS NO.:580-35-8

Empirical Formula: C23H17N

Molecular Weight: 307.39

MDL number: MFCD00014630

Pack Size Price Stock Quantity
250MG RMB228.00 In Stock
1g RMB498.40 In Stock
5g RMB1583.20 In Stock
25g RMB5519.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 139.0 to 143.0 °C
Boiling point: 220-230 °C(Press: 0.3 Torr)
Density  1.103±0.06 g/cm3(Predicted)
storage temp.  Sealed in dry,Room Temperature
form  powder to crystal
pka 3.95±0.10(Predicted)
color  White to Almost white
λmax 312nm(EtOH)(lit.)
InChI InChI=1S/C23H17N/c1-4-10-18(11-5-1)21-16-22(19-12-6-2-7-13-19)24-23(17-21)20-14-8-3-9-15-20/h1-17H
InChIKey FRZHWQQBYDFNTH-UHFFFAOYSA-N
SMILES C1(C2=CC=CC=C2)=NC(C2=CC=CC=C2)=CC(C2=CC=CC=C2)=C1

Description and Uses

2,4,6-Triphenylpyridine, as a well-known electron-deficient heterocyclic unit, has been widely used as the conjugated molecular bridge linker to the polymer main chain. Pyridine and aromatic heterocyclic derivatives have been widely used as electron transporting/hole blocking materials in LED devices and LED blends because these units have many excellent properties of being a better chromophore, with high electron affinity, high thermal and oxidative stability, and ability for good charge injection and transporting building blocks[1].
In addition, introduction of the pyridinyl moiety into the polymer backbone not only increases the electron affinity of the polymer, which makesthepolymer moreresistantto oxidation and also gives the polymer better electron-transporting properties, but also avoids fluorescence quenching due to the intersystem crossing (ISC) effect of the heavy atom. Some of them have been introduced into the polymer backbones to realize the desirable opto electronic materials.

2,4,6-Triphenylpyridine is a pyridine compound that acts as a neutral leaving group in palladium(0)-catalysed nucleophilic allylation reactions. In addition, three novel conjugated polymers based on the 2,4,6-triphenylpyridine moiety can be synthesised via the palladium-catalysed Sonogashira coupling reaction. These three polymers, P-1, P-2 and P-3, all exhibit strong fluorescence emission, characterised by a large Stokes shift and high quantum yield.

Safety

Symbol(GHS) 
GHS05,GHS06
Signal word  Danger
Hazard statements  H315-H335-H413-H318-H301
Precautionary statements  P264-P270-P301+P310-P321-P330-P405-P501-P280-P305+P351+P338-P310-P264-P280-P302+P352-P321-P332+P313-P362
HS Code  2933.39.9200

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