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BD3160245

Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II) , 97% , 92361-49-4

CAS NO.:92361-49-4

Empirical Formula: C46H47ClP2Ru

Molecular Weight: 798.35

MDL number: MFCD09038426

Pack Size Price Stock Quantity
250mg RMB80.80 In Stock
1g RMB206.40 In Stock
5g RMB882.40 In Stock
25g RMB3784.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 128 °C (D)
storage temp.  2-8°C
solubility  Soluble in dichloromethane, chloroform, toluene, tetrahydrofuran.
form  Powder
color  orange
Sensitive  Air Sensitive
Stability: store cold
InChI InChI=1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;-1;;/p+1
InChIKey BIQPPPXMBGVBDQ-UHFFFAOYSA-O
SMILES P(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)[Ru+2]1234(C5(C)=C1(C)C2(C)=C3(C)[C-]45C)([Cl-])P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

Description and Uses

Catalyst employed in the cycloaddtion of azides with acetylenes giving exclusively the 1,5-disubstitutedtriazoles in contrast to the 1,4-regiochemistry commonly observed with copper catalysis. Ruthenium catalysis also enables the use of internal acetylenes in these "click cycloaddtions".

Safety

WGK Germany  3

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