BD3160245
Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II) , 97% , 92361-49-4
CAS NO.:92361-49-4
Empirical Formula: C46H47ClP2Ru
Molecular Weight: 798.35
MDL number: MFCD09038426
Pack Size | Price | Stock | Quantity |
250mg | RMB80.80 | In Stock |
|
1g | RMB206.40 | In Stock |
|
5g | RMB882.40 | In Stock |
|
25g | RMB3784.00 | In Stock |
|
others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
Melting point: | 128 °C (D) |
storage temp. | 2-8°C |
solubility | Soluble in dichloromethane, chloroform, toluene, tetrahydrofuran. |
form | Powder |
color | orange |
Sensitive | Air Sensitive |
Stability: | store cold |
InChI | InChI=1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;-1;;/p+1 |
InChIKey | BIQPPPXMBGVBDQ-UHFFFAOYSA-O |
SMILES | P(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)[Ru+2]1234(C5(C)=C1(C)C2(C)=C3(C)[C-]45C)([Cl-])P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1 |
Description and Uses
Catalyst employed in the cycloaddtion of azides with acetylenes giving exclusively the 1,5-disubstitutedtriazoles in contrast to the 1,4-regiochemistry commonly observed with copper catalysis. Ruthenium catalysis also enables the use of internal acetylenes in these "click cycloaddtions".
Safety
WGK Germany | 3 |