Bromopentacarbonylrhenium(I) , 98% , 14220-21-4

Synonym(s):
Pentacarbonylbromorhenium;Pentacarbonylrhenium bromide;Rhenium(I) pentacarbonyl bromide

CAS NO.：14220-21-4

Empirical Formula: C5BrO5Re

Molecular Weight: 406.16

MDL number: MFCD00013295

EINECS: 238-084-8

PRODUCT Properties

• Melting point: 90°C (subl.)
• storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
• form: crystal
• color: off-white
• Water Solubility: Insoluble in water.
• Sensitive: Moisture Sensitive
• InChI: 1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
• InChIKey: NWJBOTGGBYFKEJ-UHFFFAOYSA-M
• SMILES: Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
• CAS DataBase Reference: 14220-21-4

Description and Uses

This is used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes. The starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion.

Safety

• Symbol(GHS): GHS06
• Signal word: Danger
• Hazard statements: H301+H311+H331-H315-H319-H335
• Precautionary statements: P261-P280-P301+P310-P302+P352+P312-P304+P340+P311-P305+P351+P338
• target organs: Respiratory system
• PPE: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• Hazard Codes: T
• Risk Statements: 23/24/25-36/37/38
• Safety Statements: 26-28-36/37/39-45
• RIDADR: UN 3288 6.1/PG 3
• WGK Germany: 3
• HazardClass: 6.1
• PackingGroup: II
• HS Code: 29310099
• Storage Class: 6.1D - Non-combustible acute toxic Cat.3; toxic hazardous materials or hazardous materials causing chronic effects
• Hazard Classifications: Acute Tox. 3 Oral; Eye Irrit. 2; Skin Irrit. 2; STOT SE 3