Pentacarbonylchlororhenium(I) , 98% , 14099-01-5

Synonym(s):
Rhenium(I) pentacarbonyl chloride

CAS NO.：14099-01-5

Empirical Formula: C5ClO5Re

Molecular Weight: 361.71

MDL number: MFCD00013296

EINECS: 237-948-1

PRODUCT Properties

• storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
• form: crystal
• color: off-white
• Water Solubility: Insoluble in water.
• Sensitive: Moisture Sensitive
• InChI: 1S/5CO.ClH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
• InChIKey: JQUUAHKBIXPQAP-UHFFFAOYSA-M
• SMILES: Cl[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
• CAS DataBase Reference: 14099-01-5

Description and Uses

Pentacarbonylchlororhenium(I) was used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands a well as to prepare [3]-ferrocenophane complexes. It has also been employed in preparation of a series of mixed-valence compounds of rhenium and iron. These compounds find application in the study of charge-transfer processes.

Safety

• Symbol(GHS): GHS06
• Signal word: Danger
• Hazard statements: H301+H311+H331-H315-H319-H335
• Precautionary statements: P261-P280-P301+P310-P302+P352+P312-P304+P340+P311-P305+P351+P338
• target organs: Respiratory system
• PPE: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• Hazard Codes: T
• Risk Statements: 23/24/25-36/37/38
• Safety Statements: 26-28-36/37/39-45
• RIDADR: UN 3288 6.1/PG 3
• WGK Germany: 3
• HazardClass: 6.1
• PackingGroup: II
• HS Code: 28369917
• Storage Class: 6.1C - Combustible acute toxic Cat.3; toxic compounds or compounds which causing chronic effects
• Hazard Classifications: Acute Tox. 3 Oral; Eye Irrit. 2; Skin Irrit. 2; STOT SE 3