Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate , 98+% , 99326-34-8

Synonym(s):
Bis(1,5-cyclooctadiene)rhodium triflate;Bis(1,5-cyclooctadiene)rhodium(I) triflate;Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

CAS NO.：99326-34-8

Empirical Formula: C17H24F3O3RhS

Molecular Weight: 468.34

MDL number: MFCD00143752

PRODUCT Properties

• Melting point: 159 °C (dec.)(lit.)
• storage temp.: Inert atmosphere,Room Temperature
• solubility: Soluble in chloroform
• form: crystal
• color: dark red
• Water Solubility: insoluble
• Sensitive: Air Sensitive
• Exposure limits: ACGIH: TWA 1 mg/m3; NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
• InChI: 1S/2C8H12.CHF3O3S.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h2*1-2,7-8H,3-6H2;(H,5,6,7);/q;;;+1/p-1/b2*2-1-,8-7-
• InChIKey: GOPBTCMAUMSOBX-QMDOQEJBSA-M
• SMILES: [Rh+].[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

Description and Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H319
• Precautionary statements: P264-P280-P305+P351+P338-P337+P313
• PPE: dust mask type N95 (US), Eyeshields, Gloves
• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazard Note: Irritant
• TSCA: No
• HS Code: 28439000
• Storage Class: 11 - Combustible Solids
• Hazard Classifications: Eye Irrit. 2