Triphenylborane , 96 , 960-71-4

Synonym(s):
Triphenylborane

CAS NO.：960-71-4

Empirical Formula: C18H15B

Molecular Weight: 242.12

MDL number: MFCD00003007

EINECS: 213-504-2

PRODUCT Properties

• Melting point: 145 °C (lit.)
• Boiling point: 203 °C/15 mmHg (lit.)
• Density: 0.898 g/mL at 25 °C
• Flash point: 1 °F
• storage temp.: Storage temp. 2-8°C
• form: Powder
• color: off-white
• Water Solubility: Soluble in aromatic solvents. Insoluble in water.
• Sensitive: Air Sensitive
• Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
• BRN: 1961313
• CAS DataBase Reference: 960-71-4(CAS DataBase Reference)
• EPA Substance Registry System: Borane, triphenyl- (960-71-4)

Description and Uses

Triphenylborane is used as a precursor in the production of pyridine-triphenylborane complex, which is used as a catalyst for the polymerization of acrylic esters. It is also used in the hydrocyanation of butadiene to adiponitrile. It is involved in the synthesis of 3-phenyl-cyclohexene by reacting with acetic acid cyclohex-2-enyl ester in presence of palladium bis(dibenzylideneacetone) and triphenylphosphine as a catalyst.

Safety

• Symbol(GHS): GHS02
• Signal word: Danger
• Hazard statements: H228
• Precautionary statements: P210
• Hazard Codes: F,Xn
• Risk Statements: 11-36/37/38-22-19-40-36/37
• Safety Statements: 16-26-33-36-24/25-22-36/37
• RIDADR: UN 1993 3/PG 2
• WGK Germany: 3
• RTECS: ED2367500
• F: 10-23
• TSCA: No
• HazardClass: 4.1
• PackingGroup: III