Bis(4-(trifluoromethyl)phenyl)phosphine , 95% , 99665-68-6

CAS NO.：99665-68-6

Empirical Formula: C14H9F6P

Molecular Weight: 322.19

MDL number: MFCD01630793

PRODUCT Properties

• Boiling point: 291.4±40.0 °C(Predicted)
• Density: 1.317 g/mL at 25 °C
• refractive index: n20/D1.512
• form: liquid
• InChI: 1S/C14H9F6P/c15-13(16,17)9-1-5-11(6-2-9)21-12-7-3-10(4-8-12)14(18,19)20/h1-8,21H
• InChIKey: LLJITAAISCMRAR-UHFFFAOYSA-N
• SMILES: FC(F)(F)c1ccc(Pc2ccc(cc2)C(F)(F)F)cc1

Description and Uses

Reactant for:

• Preparation of iron(II) chiral diimine diphosphine complexes as catalysts for asymmetric transfer hydrogenation of ketones
• Enantioselective decarboxylative allylation and ring-closing metathesis

Safety

• Symbol(GHS): GHS05,GHS06
• Signal word: Danger
• Hazard statements: H301-H318-H413
• Precautionary statements: P280-P301+P310-P305+P351+P338
• PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
• Hazard Codes: T
• Risk Statements: 25-37-41
• Safety Statements: 26-39-45
• RIDADR: UN 2810 6.1 / PGIII
• WGK Germany: WGK 3
• Storage Class: 6.1D - Non-combustible acute toxic Cat.3; toxic hazardous materials or hazardous materials causing chronic effects
• Hazard Classifications: Acute Tox. 3 Oral; Aquatic Chronic 4; Eye Dam. 1