MR0998858
97% , 18388-03-9
Synonym(s):
2-(Chloromethyl)-3-trimethylsilyl-1-propene;2-(Trimethylsilylmethyl)allyl chloride
| Pack Size | Price | Stock | Quantity |
| 5g | RMB7072.00 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Boiling point: | 162-163 °C/768 mmHg (lit.) |
| Density | 0.899 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 110 °F |
| storage temp. | 2-8°C |
| solubility | Chloroform, Methanol (Slightly) |
| form | Oil |
| Specific Gravity | 0.899 |
| color | Clear Colourless |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| BRN | 1747038 |
| Stability: | Moisture Sensitive |
| InChI | 1S/C7H15ClSi/c1-7(5-8)6-9(2,3)4/h1,5-6H2,2-4H3 |
| InChIKey | CQXWCEVXNRHUSQ-UHFFFAOYSA-N |
| SMILES | C[Si](C)(C)CC(=C)CCl |
Description and Uses
2-??(Chloromethyl)??allyl-??trimethylsilane is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-??(Chloromethyl)??allyl-??trimethylsilane was used in catalytic Sakurai reaction of a,??b-??enones.
Safety
| Symbol(GHS) |   GHS02,GHS07 |
| Signal word | Warning |
| Hazard statements | H226-H315-H319-H335 |
| Precautionary statements | P210-P233-P240-P241-P303+P361+P353-P305+P351+P338 |
| target organs | Respiratory system |
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi |
| Risk Statements | 10-36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | UN 1993 3/PG 3 |
| WGK Germany | 3 |
| TSCA | No |
| HazardClass | 3.2 |
| PackingGroup | III |
| Storage Class | 3 - Flammable liquids |
| Hazard Classifications | Eye Irrit. 2 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 |
