MR1090758
90% , 118722-54-6
Synonym(s):
Allyldimethyl(2-pyridyl)silane
| Pack Size | Price | Stock | Quantity |
| 2.5g | RMB5082.40 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Boiling point: | 104-105°C / 18 |
| Density | 0.913 g/mL at 25 °C |
| refractive index | n20/D 1.5046 |
| Flash point: | 71 °C |
| storage temp. | 2-8°C |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| InChI | 1S/C10H15NSi/c1-4-9-12(2,3)10-7-5-6-8-11-10/h4-8H,1,9H2,2-3H3 |
| InChIKey | WIRIPVDRZYVTCG-UHFFFAOYSA-N |
| SMILES | C[Si](C)(CC=C)c1ccccn1 |
Description and Uses
2-(Allyldimethylsilyl)pyridine can be used as a pyridyl transfer reagent to prepare substituted pyridine derivatives by reacting with various aryl iodides in the presence of a palladium catalyst and silver(I) oxide activator. It can also be utilized as a coupling reagent in the allylation of carbonyl compounds using a copper catalyst.
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| PPE | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| RIDADR | UN 3334 |
| WGK Germany | 3 |
| Storage Class | 10 - Combustible liquids |
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
