S1801950
ReagentPlus ,≥99% , 1122-58-3
Synonym(s):
(S)-(−)-N,N-Bis(2-diphenylphosphinoethyl)-α-methylbenzylamine
| Pack Size | Price | Stock | Quantity |
| 5G | RMB127.02 | In Stock |
|
| 25G | RMB376.35 | In Stock |
|
| 100G | RMB1103.64 | In Stock |
|
| 500G | RMB3405.31 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 63-65 °C |
| Boiling point: | 632.8±45.0 °C(Predicted) |
| pka | 7.82±0.50(Predicted) |
| form | solid |
| optical activity | [α]20/D 4.5±0.7°, c = 1% in acetone |
| BRN | 4608384 |
| InChIKey | ZVNAHLJBPYKGBV-HKBQPEDESA-N |
| SMILES | C[C@H](N(CCP(c1ccccc1)c2ccccc2)CCP(c3ccccc3)c4ccccc4)c5ccccc5 |
Description and Uses
(S)-(−)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine is a chiral ligand used to prepare its iridium complexes, applicable in the synthesis of allylic alcohols via reduction of α,β-unsaturated ketones.
Safety
| Symbol(GHS) |  GHS05 |
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 |
| PPE | Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 3259 8/PG 3 |
| WGK Germany | 3 |
| F | 1-10 |
| Storage Class | 8A - Combustible corrosive hazardous materials |
| Hazard Classifications | Eye Dam. 1 Skin Corr. 1B |
