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S407379

Methoxyallene , technicalgrade , 13169-00-1

Synonym(s):
1-Methoxy-1,2-propadiene;Methyl propadienyl ether;NSC 363923

CAS NO.:13169-00-1

Empirical Formula: C4H6O

Molecular Weight: 70.09

MDL number: MFCD00153022

Pack Size Price Stock Quantity
1g RMB512.57 In Stock
5g RMB1661.15 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 48.2℃ (760 torr)
Density  0.832 g/mL at 25 °C
refractive index  n20/D 1.429
Flash point: -29 °C
storage temp.  2-8°C
solubility  sol THF, ether, pentane, hexane, CH2Cl2, CHCl3, DMSO
form  liquid
InChI 1S/C4H6O/c1-3-4-5-2/h4H,1H2,2H3
InChIKey RRWJXAJEGRDMQH-UHFFFAOYSA-N
SMILES COC=C=C

Description and Uses

Reactant involved in:• ;Multicomponent reactions with nitriles and carboxylic acids followed by cyclocondensation for synthesis of enantiopure pyridines1• ;Intermolecular hydroamination2• ;One-pot synthesis of alkoxy and (alkylsulfanyl)-substituted pyrroles and dihydropyridines3• ;Intermolecular [4+2] cycloaddition with dienes4• ;Allenyl cyclization and subsequent transformation into dicarbonyl, cyclopentenones, and butenolide compounds5• ;Insertion reactions of C-C pi-bonds into alkylidenesilacyclopropanes6

Safety

Symbol(GHS) 
GHS02
Signal word  Danger
Hazard statements  H225
Precautionary statements  P210
PPE Eyeshields, Faceshields, Gloves
Hazard Codes  F
Risk Statements  11
RIDADR  UN 1993 3/PG 2
WGK Germany  3
Storage Class 3 - Flammable liquids
Hazard Classifications Flam. Liq. 2

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