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S658278

Potassium diphenylphosphide solution , 0.5 MinTHF , 15475-27-1

Synonym(s):
Diphenylphosphine potassium salt;KPPh2;Potassium diphenylphosphine

CAS NO.:15475-27-1

Empirical Formula: C12H12KP

Molecular Weight: 226.3

MDL number: MFCD00134530

Pack Size Price Stock Quantity
100ml RMB1146.62 In Stock
800ml RMB6327.34 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Density  0.929 g/mL at 25 °C
Flash point: −4 °F
form  liquid
BRN  4164304
InChI 1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1
InChIKey FCLYZQXPJKJTDR-UHFFFAOYSA-N
SMILES [K]P(c1ccccc1)c2ccccc2

Description and Uses


  • Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009).

  • Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007).

  • Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004).


Safety

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H225-H302-H314-H335-H351
Precautionary statements  P210-P260-P280-P305+P351+P338-P370+P378-P403+P235
target organs Respiratory system
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  F,C
Risk Statements  11-19-22-34-40-37
Safety Statements  16-26-33-36/37/39-45
RIDADR  UN 2924 3/PG 2
WGK Germany  1
1-8-10-13
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3

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