RuCl2[(R)-xylbinap][(R)-daipen] , 220114-32-9

CAS NO.：220114-32-9

Empirical Formula: C71H74Cl2N2O2P2Ru

Molecular Weight:

MDL number: MFCD09753026

PRODUCT Properties

• Melting point: 197-211 °C
• storage temp.: 2-8°C
• form: solid
• color: yellow to dark brown or green
• Sensitive: air sensitive
• InChIKey: CCDJBSCHRVEGKW-UHFFFAOYSA-N

Description and Uses

Chiral RuCl2(diphosphine)?(1,?2-?diamine) complexes catalyzes the asymetrical hydrogenation of amino ketones. E.g., hydrogenation of MeCOCH2NMe2 in presence of trans-?RuCl2[(R)?-?xylbinap]?[(R)?-?daipen] gave 79?% (S)?-?MeCH(OH)?CH2NMe2. This compound was used as a catalyst.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
• WGK Germany: 3
• HS Code: 2931.90.6000