(S)-(-)-XylBINAP , 97% , 135139-00-3

Synonym(s):
(S)-(−)-2,2′-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1′-binaphthyl;(S)-(−)-2,2′-Bis[di(3,5-xylyl)phoshino]-1,1′-binaphthyl;(S)-3,5-Xylyl-BINAP

CAS NO.：135139-00-3

Empirical Formula: C52H48P2

Molecular Weight: 734.89

MDL number: MFCD01630821

EINECS: 681-146-8

PRODUCT Properties

• Melting point: 203-206°C
• alpha: -172 º (c=1 in chloroform)
• Boiling point: 825.3±65.0 °C(Predicted)
• storage temp.: Inert atmosphere,Room Temperature
• Water Solubility: Insoluble in water
• form: crystal
• color: white to pale yellow
• optical activity: [α]/D -172°, 20, c =1 in chloroform
• InChIKey: MXGXXBYVDMVJAO-UHFFFAOYSA-N
• SMILES: C1(C2C=CC=CC=2C=CC=1P(C1=CC(=CC(C)=C1)C)C1=CC(=CC(C)=C1)C)C1C2C=CC=CC=2C=CC=1P(C1=CC(=CC(C)=C1)C)C1=CC(=CC(C)=C1)C

Description and Uses

Catalyst for:

• Asymmetric hydrogenation of benzophenone
• Regio- and stereoselective preparation of axially chiral arylnaphthalene derivatives via rhodium-catalyzed [2+2+2] cycloaddition of diynes with naphthalenepropynoic acid derivatives in the presence of chiral biaryl bisphosphine ligands
• Regiodivergent rhodium-catalyzed [(2+2)+2] carbocyclization of 1,6-enynes with Me propiolates
• Ligand controlled regioselective and stereoselective desymmetrizing rhodium-catalyzed allylic arylation of meso cyclopentene dicarbonates with arylboronic acids to form regioisomeric arylcyclopentenols
• Platinum(II) complex-catalyzed enantioselective aldol reaction with ketene silyl acetals in DMF at room temperature
• Stereoselective preparation of chiral N,O-biaryls via Rh-catalyzed [2+2+2] cycloaddition of conjugate ynamides with diynes

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P280a-P304+P340-P305+P351+P338-P405-P501a
• Risk Statements: 36/37/38
• Safety Statements: 26-37
• TSCA: No
• HS Code: 2931.90.6000