(S)-(-)-BINAP , 98% , 76189-56-5

Synonym(s):
(S)-(−)-(1,1′-Binaphthalene-2,2′-diyl)bis(diphenylphosphine);(S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene;(S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl;(S)-(−)-BINAP

CAS NO.：76189-56-5

Empirical Formula: C44H32P2

Molecular Weight: 622.69

MDL number: MFCD00010805

EINECS: 616-305-2

PRODUCT Properties

• Melting point: 283-286 °C(lit.)
• alpha: -240 º (c=0.3, toluene)
• Boiling point: 724.3±55.0 °C(Predicted)
• refractive index: -235 ° (C=0.3, Toluene)
• storage temp.: Inert atmosphere,Room Temperature
• solubility: Benzene (Slightly), Chloroform (Slightly)
• form: Crystals or Crystalline Powder
• color: White to light yellow
• optical activity: [α]20/D -222, c = 0.5 in benzene
• Sensitive: Air Sensitive
• Merck: 14,1223
• BRN: 5321444
• InChIKey: MUALRAIOVNYAIW-UHFFFAOYSA-N
• SMILES: P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC2=CC=CC=C2C=1C1C2=CC=CC=C2C=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1
• CAS DataBase Reference: 76189-56-5(CAS DataBase Reference)

Description and Uses

2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl and its rhodium and ruthenium derivatives are highly selective homogeneous catalysts used for the reduction of aryl ketones, β-keto esters, and α-amino ketones. They have also been used for asymmetric hydrogenation and hydroformylation of olefins, asymmetric Heck reactions, and asymmetric isomerizations of allyls.
Ligand used in a palladium-catalyzed, asymmetric, tandem Heck reaction-carbanion capture process leading to a synthesis of a tricyclic sesquiterpene. Also used in a ruthenium-catalyzed asymmetric hydrogenation of α,β-unsaturated acids.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P280g
• Hazard Codes: Xi,Xn
• Risk Statements: 36/37/38-20/21/22
• Safety Statements: 22-24/25-37/39-26-36
• WGK Germany: 3
• F: 8-10-23
• TSCA: No
• HS Code: 29319090