A0342756
Rutheniumacetylacetonate , 99.95%metalsbasis , 14284-93-6
Synonym(s):
2,4-Pentanedione ruthenium(III) derivative;Ru(acac)3;Ruthenium(III) acetylacetonate;Tris(acetylacetonato)ruthenium(III), Tris(pentane-2,4-dionato)ruthenium(III)
CAS NO.：14284-93-6
Empirical Formula: C15H21O6Ru
Molecular Weight: 398.39
MDL number: MFCD00000030
EINECS: 238-193-0
| Pack Size | Price | Stock | Quantity |
| 1g | RMB911.20 | In Stock |
|
| 5g | RMB3663.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 260 °C (dec.)(lit.) |
| storage temp. | Store below +30°C. |
| form | Crystalline |
| color | White |
| Water Solubility | Soluble in most organic solvents such as acetone, chlorinated hydrocarbons, alcohols, cyclohexane and benzene. Insoluble in water. |
| InChI | InChI=1S/3C5H8O2.Ru/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-; |
| InChIKey | RTZYCRSRNSTRGC-LNTINUHCSA-K |
| SMILES | [Ru](O/C(/C)=C\C(=O)C)(O/C(/C)=C\C(=O)C)O/C(/C)=C\C(=O)C |
| EPA Substance Registry System | Ruthenium, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14284-93-6) |
Description and Uses
Precursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a |
| Hazard Codes | Xi,T |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36-24/25 |
| WGK Germany | 3 |
| F | 10 |
| TSCA | Yes |
| HS Code | 28439000 |
