![(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III)Hexafluorophosphate](https://img.chemicalbook.com/CAS/20180808/GIF/676525-77-2.gif)
A0527656
(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III)Hexafluorophosphate , 99% , 676525-77-2
Synonym(s):
[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III) hexafluorophosphate;[Ir(dtbbpy)(ppy)2][PF6];Ir Photocatalyst
CAS NO.：676525-77-2
Empirical Formula: C40H40F6IrN4P
Molecular Weight: 913.97
MDL number: MFCD28369259
| Pack Size | Price | Stock | Quantity |
| 100mg | RMB367.20 | In Stock |
|
| 500mg | RMB2599.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| storage temp. | 2-8°C |
| form | crystal |
| color | yellow |
| λmax | 380nm(CH2Cl2)(lit.) |
| InChIKey | VCIVELSSYHAWGC-UHFFFAOYSA-N |
| SMILES | [P+5]([F-])([F-])([F-])([F-])([F-])[F-].C(C1=CC=N2[Ir+3]34(N5=CC=CC=C5C5=CC=CC=[C-]35)(N3=CC=CC=C3C3=CC=CC=[C-]43)N3=CC=C(C(C)(C)C)C=C3C2=C1)(C)(C)C |
Description and Uses
[Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:
- Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
- Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
- Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
- Aryl-alkyl C?C reductive cross-coupling reactions.
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315-H319 |
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 2843.90.0000 |
