Benzenesulfonyl chloride , 96% , 98-09-9
Synonym(s):
Benzene sulfochloride;Benzenesulfonyl chloride
CAS NO.：98-09-9
Empirical Formula: C6H5ClO2S
Molecular Weight: 176.62
MDL number: MFCD00007426
EINECS: 202-636-6
PRODUCT Properties
| Melting point: | 13-15 °C (lit.) |
| Boiling point: | 251-252 °C (lit.) |
| Density | 1.384 g/mL at 25 °C (lit.) |
| vapor pressure | 0.04 mm Hg ( 20 °C) |
| refractive index | n |
| Flash point: | >230 °F |
| storage temp. | Store below +30°C. |
| solubility | alcohol: soluble |
| form | Liquid |
| color | Clear |
| Water Solubility | may decompose |
| Sensitive | Moisture Sensitive |
| Merck | 14,1072 |
| BRN | 606926 |
| Stability: | Stable. Incompatible with water, strong oxidizing agents, strong bases, methyl formamide, dimethyl sulfoxide. |
| LogP | 3.39 at 23℃ |
| CAS DataBase Reference | 98-09-9(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzenesulfonyl chloride(98-09-9) |
| EPA Substance Registry System | Benzenesulfonyl chloride (98-09-9) |
Description and Uses
Benzenesulfonyl chloride is a colorless oilyliquid with a pungent odor. Molecular weight= 176.6;Specific gravity= 1.3842 at 15℃; Boilingpoint = 251- 252℃ (decomposes); Freezing/Meltingpoint= 15℃; Vapor pressure= 1 mmHg at 20℃; Relativevapor density (air=1) = 6.12; Flash point =130℃;Autoignition point = 460℃. Hazard Identification (based onNFPA-704 M Rating System): Health 3, Flammability 1,Reactivity 1. Moderately soluble in water.
Benzenesulfonyl chloride reacts with Grignard reagents to form oxindoles from N-unsubstituted indoles. It is widely used to check the assay of thiamine in different food products. It is involved in the synthesis of alpha-disulfones, sulfonamides and sulfoante esters as precursor. It is a derivatization reagent for the determination of various amines in waste water and surface water at the sub-ppb level by gas chromatography-mass spectrometry. It is common reagent used in Hinsberg test for detection and distinguishing the type of amines as primary, secondary and tertiary amines.
Safety
| Symbol(GHS) |   GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H302-H314 |
| Precautionary statements | P270-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
| Hazard Codes | C |
| Risk Statements | 20/22-34-42/43-29-22 |
| Safety Statements | 23-26-36/37/39-45 |
| RIDADR | UN 2225 8/PG 3 |
| WGK Germany | 1 |
| RTECS | DB8750000 |
| F | 21 |
| Autoignition Temperature | 450°C |
| TSCA | Yes |
| HazardClass | 8 |
| PackingGroup | III |
| HS Code | 29049090 |
| Hazardous Substances Data | 98-09-9(Hazardous Substances Data) |
| Toxicity | LD50 orl-rat: 1960 mg/kg MEPAAX 20,513,69 |
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) |
